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107年 關務特考四等 化學工程｜歷屆考題全文（機器抽取）

107年公務人員特種考試關務人員考試、107年公務人員特種考試身心障礙人員考試、107年國軍上校以上軍官轉任公務人員考試化學工程類科歷屆試題，含國文（作文、公文與測驗）、英文、法學知識（包括中華民國憲法、法學緒論）等 5 科。

共 5 份考卷｜資料來源：依政府資料開放授權條款（OGDL）第 1 版利用，資料集：考選部歷屆試題（data.gov.tw dataset 170565），107 年。

本頁文字由 PDF 機器抽取，可能有辨識誤差，僅供搜尋參考，請以官方原始檔案為準。

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國文（作文、公文與測驗）

下載：題目　答案

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：關務人員考試

等

別：四等考試

類

科：各科別

科

目：國文（作文、公文與測驗）

考試時間：

2 小時

※注意：

禁止使用電子計算器。

甲、 申論 題 部 分 ： 甲、作文與公文部分：

 請以藍、黑色鋼筆或原子筆在申論試卷上由左至右橫式作答，於本試題上作答者，不予計分。  不得於試卷上書寫姓名或入場證號。

一、作文：（ 60 分）

「跑道」可以提供飛機航班起落，也可以是田徑、滑冰種種比賽的場地。人生同樣 有千百條不同形態的「跑道」 ，可能曲徑通幽，可能荒榛密布，也可能大海阻隔，總 之一段從 A 至 B 的路程，不可能永遠是康莊坦途，或許一條岔路就改變了一生的軌 跡。試以「跑道」為題，作文一篇，抒寫自身的體悟。

二、公文：（ 20 分）

依據「行政院加速投資臺灣專案會議」相關結論，由財政部協助經濟部、交通部、 教育部、內政部、衛生福利部、文化部、行政院農業委員會、客家委員會及各直轄 市和縣市政府盤點前瞻基礎建設計畫中，可以採行促參（促進民間參與公共建設） 機制的案源，共有 20 項子計畫。

試擬財政部函請前述各機關就盤點結果持續滾動檢討，並於 107 年 6 月 30 日前將檢 討結果函復該部。

乙、測驗部分：（ 20

分）

代號： 2201

 本測驗試題為單一選擇題，請選出一個正確或最適當的答案，複選作答者，該題不予計分。  共 10 題，每題 2 分，須用 2B 鉛筆在試卡上依題號清楚劃記，於本試題或申論試卷上作答者，不予計分。

1

2

3

甲：「請問令堂能夠出席晚宴嗎？」乙：「家父明天一定準時到。」

依據上文，下列敘述何者最正確？

20120

代號：

｜

全一張

20720

（正面）

座號：

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：關務人員考試

等

別：四等考試

類

科：各科別

科

目：國文（作文、公文與測驗）

4

5

6

7

8

9

10

 文學傳統崩壞

依據上文，最能符合楚人形象的選項是：

根據上文，下列敘述何者正確？

「莫對青山談世事，此間風物屬詩人」，這副對聯主要的意思是：

 嘆獨居無聊天對象

依據上文，下列敘述錯誤的是：

依據上文，其新的實驗方法與結果為何？

符合上文旨意的選項是：

20120

代號：

｜

20720

全一張

（背面）

英文

下載：題目　答案

代號：

4201

頁次：

4

－

1

107 年公務人員特種考試關務人員、身心障礙人員考試及 107 年國軍上校以上軍官轉任公務人員考試試題

考 試 別：

關務人員考試

等 別：

四等考試

類

科： 各科別

科 目：

英文

考試時間：

1 小時

座號：

※注意：

本試題為單一選擇題，請選出一個正確或最適當的答案，複選作答者，該題不予計分。

本科目共

50

題，每題

2

分，須用

2B

鉛筆在試卡上依題號清楚劃記，於本試題上作答者，不予計分。

 禁止使用電子計算器。

頁次：

4

－

1

with ease

in line

at their loss

Could

Can't

assuming

overseeing

propelling

assessing

prescribed

nominated

discarded

delinquents

hypocrites

 immigrants

 sanctions

請依下文回答第

11

題至第

15

題

The Slow Food movement was initiated when a European journalist, Carlo Petrini, saw that a fast-food restaurant had opened in a beautiful square in Rome. He thought it was tragic that many people today live too 11 to sit down for a proper meal and only eat 12 fast food. He decided that he has to try to do something about it, 13 he started the Slow Food movement. 14 he didn't succeed in banning that fast-food restaurant, Slow Food has become a global organization and now has more than 80,000 members in 100 countries.

Slow Food also encourages people to eat local and regional food, to use local shops and markets, to eat out in small family restaurants, and to cook 15 traditional recipes. As member Jon Winge says, "I think it's such a cool idea. You support the people who produce beautiful products for you.'

11  quickly

 quick

 quietly

 quiet

12  mass-producing

mass-produced

 mass-production

 mass-produce

13  but

 still

 yet

 so

14

Because

Once

 Although

 Since

15  as

with

at

 below

請依下文回答第

16

題至第

20

題

When a melting glacier released its hold on a 4,000-year-old corpse in September, it was quite rightly called one of the most important archaeological findings of the century. 16 by a German couple hiking at 10,500 feet in the Italian Tyrol near the Austrian border, the partially freeze-dried body still wore remnants of leather garments and boots that had been 17 with straw for insulation. At his side was a bronze ax of a type 18 in southern central Europe around 2000 B.C. On his expedition he had carried an all-purpose stone knife, a wooden back-pack, a bow and a quiver, a small bag 19 a flint lighter and kindling, and an arrow repair kit in a leather pouch. Such everyday gear gives an unprecedented perspective on life in early Bronze Age Europe. 'The most exciting thing is that we genuinely appear to be looking at a man who had some kind of 20 in the course of a perfectly ordinary trip,' says archaeologist Ian Kinnes of the British Museum. 'These are not artifacts placed in a grave, but the fellow's own possessions.'

16

Endured

Enduring

 Discovered

 Discovering

17

split

stuck

stuffed

 spoiled

18

typical

tropical

tragical

 technical

19

interacting

deducting

alternating

 containing

20

ache

accent

accident

 attraction

請依下文回答第 21 題至第 25 題

Scientists in the United States are planning to create lie-detection software for emails and text messages. The new software is being developed by a team led by Jeff Hancock at Cornell University in New York State. "We asked people to come into the labs and write lies and we had other people come in and write the truth," says Hancock. "Using this method, we've developed a database of tens of thousands of emails.'

The scientists have analyzed the data and identified a number of methods to predict whether or not a person is lying. One of the most important methods is the length of a message. Lying emails have, on average, 28% more words than truthful messages. Another method is the overuse of sense words, such as "see," "feel," and "touch." "When you're lying, you want the other person to believe you, so you give more details," says Hancock.

Liars also tend to use pronouns like "we" and "they" rather than "I" as a way of distancing themselves from a lie because they feel guilty. "People often use negative emotional words too, because they feel uncomfortable when they're lying," says Hancock. "So they will use terms like "sad," "angry," "unhappy" and "stressed."

Previous research has shown that up to one third of communications at work involve lying of some sort. The most common workplace lie is pretending to be sick to avoid going to work.

But Peter Collett, a psychologist who has written a book on lying, is skeptical about Hancock's work. "You can see if somebody is lying by looking at their body language, how fast they talk, and how they speak," he says. "How can a computer program see all this? They've clearly done a lot of research, but with emails all you have is words."

請依下文回答第 26 題至第 30 題

Cyberbullying is bullying that takes place using electronic technology. Electronic technology includes 26 and equipment such as cell phones, computers, and tablets as well as communication tools including social media sites, text messages, chat, and websites. Examples of cyberbullying include mean text messages or emails, rumors sent by email or posted on social networking sites, and 27 pictures, videos, websites, or fake profiles. Kids who are being cyberbullied are often bullied in person as well. Additionally, kids who are cyberbullied have a 28 time getting away from the harm. Cyberbullying can happen 24 hours a day, 7 days a week, and reach a kid even when he or she is alone.

Cyberbullying messages and images can be posted anonymously and 29 quickly to a very wide audience. It can be difficult and sometimes impossible to trace the source. Deleting inappropriate or harassing messages, texts, and pictures is extremely difficult after they have been posted or sent.

Cell phones and computers themselves are not to blame for cyberbullying. Social media sites can be used for 30 activities, like connecting kids with friends and family, helping students with school, and for entertainment. But these tools can also be used to hurt other people. Whether done in person or through technology, the effects of bullying are similar.

 anxious

請依下文回答第 31 題至第 35 題

When people talk about Concorde, they tend to describe it the way one might describe Princess Diana: charming, elegant, and classic. The retired supersonic passenger airliner, still 31 a remarkable achievement of the engineering, first entered service in 1976. It had the most powerful and efficient engines at supersonic speeds. During flight, it would stretch between 6 and 10 inches from its normal length, 32 the heating of the airframe. A special white paint was thus used to help reflect and radiate the heat.

Concorde used to fly regularly from London and Paris to New York and Washington. It flew these routes in 33 half the time of other airlines. A trip from London to New York with Concorde took nearly three hours and thirty minutes as opposed to eight hours with Boeing 777 or Airbus 330. That is to say, it was not 34 for business people to take a day trip to New York and return home in London before pubs closed. With only 20 aircraft built, 35 , Concorde was not a success in terms of economic profit. After the aircraft's only crash in 2000 and the 911 terrorist attack in 2001, Concorde was retired in 2003, bringing to an end the era of supersonic passenger transportation.

31  thought up  regarded as  consisted of  identified with 32  as for  due to  instead of  aside from 33  less than  much less  much more  more than 34  potential  uncommon  irresistible  aggressive 35  therefore  otherwise  however  moreover

請依下文回答第 36 題至第 40 題

The Pathways Programs offer clear paths to Federal internships for students from high school through post-graduate school and to careers for recent graduates, and provide meaningful training and career development opportunities for individuals who are at the beginning of their Federal service. As a student or recent graduate, you can begin your career in the Federal government by choosing the path that best describes you and where you are in your academics:

For additional information on the Pathways Programs overall, please visit http://www.opm.gov/HiringReform/Pathways/.

請依下文回答第 41 題至第 45 題

Marianne Moore (1887-1972) once said that her writing could be called poetry only because there was no other name for it. Indeed her poems appear to be extremely compressed essays that happen to be printed in jagged lines on the page. Her subjects were varied: animals, laborers, artists, and the craft of poetry. From her general reading came quotations that she found striking or insightful. She included these in her poems, scrupulously enclosed in quotation marks and sometimes identified in footnotes. Of this practice, she wrote, ''Why the many quotation marks?' I am asked. . . when a thing has been said so well that it could not be said better, why paraphrase it? Hence my writing is, if not a cabinet of fossils, a kind of collection of flies in amber.' Close observation and consentration on detail are the methods of her poetry.

Marianne Moore grew up in Kirkwood, Missouri, near St. Louis. After graduation from Bryn Mawr College in 1909, she taught commercial subjects at the Indian school in Carlisle, Pennsylvannia. Later, she became a librarian in New York City. During the 1920's, she was editor of The Dial , an important literary magazine of the period. She lived quietly all her life, mostly in Brooklyn, New York. She spent a lot of time at the Bronx Zoo, fascinated by animals. Her admiration of the Brooklyn Dodgers-before the team moved to Los Angeles-was widely known.

Her first book of poems was published in London in 1921 by a group of friends associated with the imagist movement. From that time on, her poetry has been read with interest by succeeding generations of poets and readers. In 1952, she was awarded the Pulitzer Prize for her Collected Poems . She wrote that she did not write poetry 'for money or fame. To earn a living is needful, but it can be done in routine ways. One writes because one has a burning desire to objectify what is indispensable to one's happiness to express....'

請依下文回答第 46 題至第 50 題

Are you interested in making a French omelet? Below are some steps you may follow:

First, whisk together the eggs until just mixed, then season. Lay out any fillings by the hob. Second, heat a pan over a medium-high flame and add the butter and ' swirl ' to coat. When the foam begins to die down, pour in the eggs. They should sizzle. Third, shake the pan to distribute the eggs evenly, then leave for 20 seconds until they begin to bubble. Add any filling such as onion, corn, mushrooms, etc. Next, use a fork to draw in the sides of the eggs to the center while shaking the pan to redistribute the liquid to the edges. The omelet is done when still slightly runny in the middle. Finally, take off the heat, and fold two edges into the middle. Shake the pan so they roll together, then tilt it and turn your omelet on to a warm plate (you can tidy it up before serving if you like). Season with salt and pepper, and then eat immediately!

What's your favorite omelet recipe, and are you a stirrer or a shaker? And can these delicate French omelets ever compete with a whopping British half moon, oozing with cheese, and served with chips?

26  directions  decisions  devices  defenses
27  promising  embarrassing  blessing  confessing
28  harder  shorter  better  tender
29  discouraged  disconnected  distributed  distinguished
30  intensive  positive  restrictive  expensive

法學知識（包括中華民國憲法、法學緒論）

下載：題目　答案

座號：

107 年公務人員特種考試關務人員、身心障礙人員考試及 107 年國軍上校以上軍官轉任公務人員考試試題

考 試 別：

關務人員考試、身心障礙人員考試

等 別：

四等考試

類

科： 各科別、各類科

科 目：

法學知識（包括中華民國憲法、法學緒論）

考試時間：

1 小時

代號：

1201

頁次： 4 － 1

※注意：

 本試題為單一選擇題，請選出一個正確或最適當的答案，複選作答者，該題不予計分。

 本科目共 50 題，每題 2 分，須用 2B 鉛筆在試卡上依題號清楚劃記，於本試題上作答者，不予計分。  禁止使用電子計算器。

 公共場所中沒有隱私權，因個人已經同意暴露在公眾的注視下，而沒有合理隱私期待

 公共場所中仍有隱私權，個人只要是從事私人活動，均得主張免於他人注視或監看

 公共場所中仍有隱私權，狗仔隊得否跟拍名人，仍應個案權衡

 公共場所中沒有隱私權，國家實施臨檢之場所，以公共場所為限

 總統依法行使大赦權

 議決條約

 大赦案須經行政院會議議決、向立法院提出

行政院對立法院通過之大赦案，得提出覆議

 我國並無「政黨法」，政黨之成立由人民團體法規範

 公務人員得組織工會

 犯罪性質之結社，得限制之

受國民教育之權利

 課程設計

 學生成績評量

 受教育之公平機會

 全國性公共政策（如設立博弈特區等）

 複決權

 服公職權

人民因犯罪被逮捕拘禁，在逮捕拘禁為違法的前提下，本人或他人得聲請法院於

非由法院依法定程序，不得審問處罰。此處的「法院」限於法官，不包括檢察官

15

下列何者非屬司法院大法官之職權？

解釋憲法

調查及處理不當黨產案件

審理政黨違憲解散案件

統一解釋法令

18

憲法所稱固有疆域範圍之界定，大法官在司法院釋字第

法律行為

統治行為

328

號解釋中，稱之為何種行為？

政治行為

立法行為

22

關於人民聲請解釋憲法，下列敘述何者錯誤？

政黨得為聲請人

聲請人須用盡通常救濟途徑

聲請人須主張憲法上之權利遭受不法侵害

聲請釋憲之標的為所有公權力行為

25

下列那一項憲法規定或原則，並非司法院大法官解釋所指明的修憲界限？

國民主權原則

保障人民權利之規定

權力分立原則

權力分立與制衡之原則

24

小時內提審

 在專屬授權範圍內，著作財產權人不得行使權利

對犯罪之幫助，必須對犯罪具有效助力

 租賃契約為財產權利用型契約

 租賃契約為要式契約

繼續性供給契約

消費借貸契約

權力分立

保障基本人權

司法審查

行政院院長任期

英美法系

國內法

北歐法系

實體法

 英美法系國家中，不可能有成文法典

歐陸法系

任意法

租賃契約

 承攬運送契約

遠東法系

行政法

有機化學概要

下載：題目

官方不公布申論答案

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：

關務人員考試

等 別：

四等考試

類 科：

化學工程

科 目：

有機化學概要

考試時間 ：

1 小時 30 分

※注意：  禁止使用電子計算器。

 不必抄題，作答時請將試題題號及答案依照順序寫在試卷上，於本試題上作答者，不予計分。  本科目除專門名詞或數理公式外，應使用本國文字作答。

一、請寫出下列反應式之主要產物。 （請表示正確的化學式，每小題 4 分，共 40 分）

O

N

H

催化量

, H 2 C(CN) 2

O

O

EtO C

Cl

NaOEt;

NH+

Cr

O

O

O-

O

Cr

O

O

-O

OH

OH

2.5

當量

PDC, DMF

PDC =

+HN

CO2Me

2.1

當量

PhMgBr; H 2 O

t

BocN CH 2 CO 2 H +

H

PhCHCO2Me

NH2

N C N

(DCC)

O

O

t

Boc =

EtO 2 C

CO2Et

1.05

當量

NaOEt; H 3 O

代號： 20630

全三頁

第一頁

座號：

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：

關務人員考試

等 別：

四等考試

類 科：

化學工程

科 目：

有機化學概要

NMe2

N2Cl

CH3

CO2H

微量

P, Br 2

Cl

O

(CH3 ) 2 CuLi; H 2 O

  1. BH 3 , THF

  2. 30%H 2 O 2 , NaOH (aq.)

二、請寫出下列反應之反應機構。 （每小題 10 分，共 40 分）

O

H2N-NH2, NaOH(aq.)

N 2

加熱

CHO

EtO 2 C

CH2

PPh 3 Br

CO2Et

NaH,

THF

CH3

CH3

OH

H Br

Br 2 , CH 3 CN / H 2 O

AlCl 3 , CH 3 CH2CH2Cl

（請接第三頁）

代號：

20630

全三頁

第二頁

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：

關務人員考試

等 別：

四等考試

類 科：

化學工程

科 目：

有機化學概要

Br

Br

NO2

NO2

OMe

NaOMe

NaOMe

沒有反應

加熱

加熱

Br

NO2

NO2

OMe

OMe

NO2

OMe

Br

四、請完成下列的合成（可使用任何無機試劑） 。 （ 10 分）

NH

O

O

Br

H3CO

NH2

H3CO

Hint: Gabriel Synthesis

（請接背面）

代號： 20630

全三頁

第三頁

分析化學概要

下載：題目

官方不公布申論答案

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：

關務人員考試

等 別：

四等考試

類 科：

化學工程

科 目：

分析化學概要

考試時間 ：

1 小時 30 分

代號： 20650 全一張 （正面）

座號：

※注意：

 可以使用電子計算器。

不必抄題，作答時請將試題題號及答案依照順序寫在試卷上，於本試題上作答者，不予計分。

三、進行酸鹼滴定需要配置標準酸液和標準鹼液。

O

OH

O

K +

O

107 年公務人員特種考試關務人員、 身心障礙人員考試及 107 年國軍上校 以 上 軍 官 轉 任 公 務 人 員 考 試 試 題

考 試 別：

關務人員考試

等 別：

四等考試

類 科：

化學工程

科 目：

分析化學概要

樣品

濃度

樣品

濃度

樣品

濃度

樣品

濃度

樣品

濃度

代號： 20650 （背面）

全一張

1 9.53 6 10.85 11 11.46 16 9.79 21 10.04
2 8.99 7 11.15 12 8.70 17 8.96 22 10.24
3 9.89 8 9.88 13 9.95 18 9.20 23 9.40
4 10.00 9 9.81 14 11.02 19 10.22 24 10.84
5 9.80 10 10.17 15 10.28 20 9.49 25 10.60
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